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ARTICLES FROM BACK ISSUES OF UNDERWATER MAGAZINE
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Underwater contractors, oil operators, and equipment manufacturers use "environmentally friendly" or "green" lubricants that should protect them against oil spill damages and costs. However, some unscrupulous oil suppliers have confused the market. Terresolve's Mark Miller, Shari Miller, and Curt Scharf help separate fact from fiction. There is growing concern over the environmental impact and associated costs of lost petroleum-based fluids. The US National Oceanic and Atmospheric Administration (NOAA) estimates over 700 million gallons of petroleum enter the environment each year, over half of which is due to irresponsible and illegal disposal. It is estimated that up to 80 percent of hydraulic fluids leave systems through leaks, spills, line breakage, and fitting failure. Petroleum is persistent and toxic. It damages living organisms, including plants, animals, and marine life, for many years. In addition, the US Coast Guard, Environmental Protection Agency (EPA), and local governments are increasing the range of responsibility of lubricant releases, including significant fines and clean-up costs. There are many different contributors to oil released into the ocean, including oil spills, routine maintenance, and natural seeps. As demands on lubricant systems increase, the likelihood of accidental fluid release increases. Increased operating temperatures, pressures, and working cycles shorten the life of circuit components.
The single best approach to protecting the environment, the
equipment, and the operation is to prevent leaks and spills through
good routine maintenance. A good preventative maintenance program
will:
Myth 1: The Coast Guard Approves Non-Sheening Oils While spilling large quantities of biodegradable hydraulic fluid is still considered under RCRA to be a reportable event, agencies are required to evaluate "bio-based oils" differently than petroleum-based oils. As awareness of biodegradable fluids increases, state and federal agencies become more lenient regarding fines and clean-up costs. In fact, there are many case studies of equipment releasing several hundred gallons of vegetable-based hydraulic fluid into environmentally sensitive areas with no fines and minimal clean-up expense. In most instances, the operator was able to continue working during clean-up efforts. Since the fluids were biodegradable and non-toxic, there was no long-term negative effect to the ecosystem. There is a common misperception that the Coast Guard approves oils based on the oil not leaving a sheen. This is not true. The Coast Guard does not approve, recommend, nor endorse any fluids. Furthermore, the Coast Guard does not approve nor recommend any test procedures, but rather, follows United States statute laws. The oil sheen that is frequently referenced is inferred from the Clean Water Act as defining "any substance that leaves a sheen, emulsification, or discoloration, as a pollutant and be subject to appropriate fines and regulations governing pollutants." The Coast Guard also relies on the guidelines as outlined by equipment manufacturers and highly favors the use of bio-based and biodegradable fluids.
Myth 2: "Inherently Biodegradable" Products are Environmentally Safe Despite these definitions, there are two widely used designations for biodegradability, readily and inherently. Readily biodegradable is defined as degrading 80 percent within 21 days as measured by the decrease of a test sample. This degradation is preferable because, in most cases, the fluid will degrade long before environmental damage has occurred. Thus, they require little in terms of long-term bio-remediation. Vegetable-based lubricants and some synthetic ester-based products exhibit ready biodegradation. There are several petroleum-based lubricants that claim "inherent biodegradability," defined as having the propensity to biodegrade, with no indication of timing or degree. These products can persist in the environment for years, continuing to cause substantial damage. They require long-term remediation due to the environmental persistence. Typically, these products are petroleum-based, like conventional lubricants. It is easy for the EPA and Coast Guard to see the difference between a readily biodegradable product and an inherently biodegradable one, and they utilize this differentiation when evaluating an oil release.
Myth 3: Food-Grade Products are Environmentally Safe Depending on the tests and its end points, the toxicity of a fluid is described by a loading rate that has a 50 percent effect (EL50) or causes 50 percent mortality (LL50) after the stated time. That is, at what concentration of fluid one half of the sample organisms die. Attempts have been made using "food-grade" lubricants to protect the environment. While food-grade oils seem like a good idea, it is highly impractical for underwater applications. First, food-grade products are designed for equipment in food processing plants. They are toxic. In fact, an entire batch of food must be discarded in the event of contact with the lubricant. Secondly, they are environmentally persistent (non-biodegradable), meaning they are toxic to marine life for long periods of time. Lastly, they are designed for very light duty usage and break down quickly under typical pile driving temperatures and pressures.
Myth 4: All Biodegradable Products Work the Same It was a great idea, but it didn't work. The characteristics of vegetable oils are vastly different than those of petroleum oils. Vegetable oils had to be formulated for their individual strengths and limitations. Today, there are several vegetable-based products on the market. They offer good performance and a fair price. While all vegetable-based lubricants have temperature limitations, there are some that are better than others. One should check with their lubricant supplier to determine their maximum and minimum operating temperatures. While most vegetable-based lubricants have a maximum operating temperature of 140 degrees F, some offer protection as high a 220 degrees F. Similarly, most vegetable-based lubricants offer good performance to 30 degrees F, yet there are some that flow below -30 degrees F. When an environmentally preferable product is required outside the common temperatures range, a biodegradable synthetic is usually required. While offering biodegradation, these products can operate in temperatures in excess of 400 degrees F and still offer long fluid life. As would be expected, these products are significantly more expensive. Care must be taken in choosing the appropriate product for the specific application. Responsible environmentally preferable product (EPP) suppliers can clearly indicate their definition of "environmentally preferable." The Federal Trade Commission has been very specific in their requirements for environmental claims and state, "Look for claims that give some substance to the claim, the additional information that explains why the product is environmentally friendly." Many would-be EPP suppliers use misleading environmental claims such as "inherently biodegradable" or "food grade." Suppliers should be able to support performance claims with testing data. These data can include standard industry tests (ASTM), field-testing, and equipment manufacturer tests. Unless an EPP supplier specializes in environmentally preferable products, they are probably not expert in the field.
Myth 5: Using a Biodegradable Product Will Void Your Warranty Biodegradable fluids have been used in various other industries from many years. As such, even if an equipment manufacturer has not given their approval for biodegradable fluids, there is a good likelihood that a high-quality fluid will have multiple equipment component manufactures' approvals. Check with the lubricant supplier as to additional approvals.
Protect the Environment, Save Money
While underwater users are trying their best to adhere to the
regulations, there is still much confusion regarding biodegradable
oils and the regulations pertaining to them. In an attempt to clarify
some of this confusion, here are some important points to remember:
With proper maintenance and routine monitoring, biodegradable fluids
will provide a long useful life for the fluid and the equipment.
Lastly, no one wants a lubricant spill, but they are a fact of life.
In this circumstance, biodegradable lubricants will more than pay for
themselves in terms of reduced clean up costs, fines, downtime and
administrative costs. UW
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